I've several times talked to engineers at the companies that make the vinyl sheeting (not completed liners) and they tell me it is NOT true. In any case, if you did have loss of calcium chloride, it wouldn't make the vinyl brittle. PVC is naturally brittle, with or without calcium carbonate filler -- you have to add a plasticizer to make it flexible. Loss of plasticizer WILL make it brittle.
As Waterbear notes, it's not exactly a coincidence.
As best I can tell, the toxicity issue applies primarily to folks who have (a) male dogs who (b) drink a lot of pool water, and (c) have not been fixed, but are planned (d) for breeding. Significant borate ingestion can impair canine fertility and is possibly mutagenic. One of the other PF Support Team members does not use borates because she breeds German Shepherds and they do drink a lot of pool water.


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