If your chlorine is low (below 5ppm), then you don't need to use the distilled water to test pH. That dilution method is only necessary if your chlorine reading is over 5ppm.
Get some chlorine in that pool asap! While you are just using bleach, your chlorine is going to disappear fast since you have no CYA in the pool yet. For now, you probably need to add bleach a couple of times per day so it never drops down to 0 like it apparently did today. That is an open invitation to algae! It doesn't take long for a pool to turn green!
Whether to cover the pool is strictly a matter of preference. It will use less chlorine without the sun's rays hitting the water. But, whether the cover is on or not, you still need to run your pump/filter for several hours per day.
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