Do *NOT* shock (raise the chlorine level suddenly). You NEVER want to do that when you have metals in the water, unless you have a specific case, and are trying to drop all the metals to the bottom --you can do that with iron, but not copper.
Polyquat is a good backup. It not only will help filter the metals out, as they precipitate, but it will reduce the need to 'shock' to control algae.


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