Can't tell enough from the picture, to answer questions based on it.
+ Any PVC glue will work with PVC. Read the labels and follow instructions. Some of it will be overkill, but better that than joint failure!
+ The white compound is just oxidized PVC glue -- color doesn't really matter.
+ PVC valves can either be threaded or socket (glued).
+ The questions you are asking make me nervous. Many SWCG cells are one-shot install: if you screw it up, you may have to buy a new cell, or at the lease, overpriced & expensive replacement unions. Consider hiring it done.
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