Hi Arid;
Sorry it's taken me so long to reply. I enhanced the contrast on your first photos a bit - I don't thing that's algae. I'd bet on it either being iron OR some discoloration of any organic binders in the finish. You can test, this way:
1. Turn off your pool pump.
2. Take either some chlorine powder OR a piece of a chlorine tablet, and put it on one of the brown 'algae' marks.
3. On the OPPOSITE side of the return, put a handful of Vitamin C tablets on another mark. Make sure the tablets are clustered together -- chlorine destroys vitamin C, so you want enough tablets piled up, so that the vitamin C on the bottom of the pile is not destroyed.
4. Wait 1/2 hour, and then remove the tablets or powder. (If they've dissolved or are just a powder, you can just sweep what's left out into the pool.
5. Check the spots underneath.
(a) If it's algae, the spot under the chlorine should be clear, but there will be little or no effect under the vitamin C.
(b) If it's iron, the spot under the Vitamin C should be lighter, but the spot under the chlorine will probably show no effect.
(c) If it's organic + chlorine, then the spot under the chlorine may be darker (or not) and the spot under the Vitamin C should be unaffected.
Regarding your calcium -- get some distilled water (distilled, NOT spring water or anything else). Wamart has it in gallon jugs, for about $1 in my area.
Great Value: Distilled Water, 1 Gal
Take a mixing cup and fill it 1/3 with pool water, and 2/3 with distilled water, making 1 cup. Mix, and then run your calcium test on THAT mixture. Multiple the result by THREE.
Very high calcium can complicate pool chemistry in a variety of ways.
Regarding your OTO result -- that is 'out of range' in the sense that it doesn't match any results on the color block. But it's not out of range for the OTO reagent -- that color corresponds approximately to chlorine in the 20 - 35 ppm range. That's a good level for clearing algae in a pool with CYA = 70 ppm. Read the "Best Guess" page linked in my signature for more information.
But, as I said, I doubt that your problem is algae.
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