No idea.
Two things you can try:
1. Get some Vitamin C tabs (ascorbic acid) and hold them against the stained area for several minutes. If it's an iron stain, you'll see some definite lightening. And, then, we'll be able to tell you how to remove it.
2. Take some pictures, and send them to poolforum@gmail.com. To help, they'll need to be LARGE in-focus pictures. Cell phone pictures might help, but probably won't.
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