Add it DIRECTLY to your skimmer, BUT
1. Make 1,000% sure that there are no chemicals of any kind anywhere in the lines or pump, between the skimmer and the filter.
2. Don't add when you've just backwashed the filter; wait till the pump has run 12 hours and loaded a little dirt into the filter.
Just remember, except for borax, cal hypo reacts BADLY with almost everything, including Coke, stabilizer, trichlor, dichlor, and more. It's fine once it's fully dissolved, and the filter will hold it, till it dissolves.
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