You can order replacement bottles of the reagents from several places online. I personally get most of mine from spspoolspas.com, but you can also get them from taylortechnologies.com and other places--they are basically Taylor reagents.
Depending on how often you test for certain things, you may not need the bigger kit. I have a similar kit (the one that Ben used to sell on this site but doesn't anymore) that had the small bottles of reagents, but I just buy the CYA and DPD-FAS drops and powder in larger quantities. I have a high CYA pool, so I use more of those particular reagents than the others. I only test for TA a couple of times a year and calcium almost never (vinyl pool, no cal-hypo), so it takes a LONG time for me to use up either of those.
If you store the kit inside away from sunlight, humidity, and temperature extremes, then the reagents in my experience are good for at least 2 years, with the exception of the DPD powder, which needs to be replaced when it gets gray and starts clumping--I usually replace mine every spring.
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