Thanks for your advice.
The guys who installed the coping already tried to get those marks out -- they did a very light acid wash -- and nothing happened - you see them as they were.
On a separate test piece I tried TSP and that did not work - stained the piece even worse.
So you suggest:
1. Grout the coping
2. Put in the expansion joint between the coping and the deck pavers (which are in sand)
3. Use the pool for a season - even though the coping shows the alkalie marks as well after they are wet.
4. At the end of the season, then do a light acid wash again.
Is that about it?
Again, thanks for posting and for your advice.
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