Some. Not 4ppm between 8 & noon.
A typical commercial pool with 120,000 gallons and 200 ppd may have to add 5 - 10 pounds of cal hypo 2x per day to maintain good chlorine levels all day. But, that's 16 ppd / 10,000 gallons, where your pool is 1.5 ppd per 10,000 gallons. The only things I can think of are:
1) Your CYA test results are mistaken.
2) You've added bromine without knowing it -- very possible; those products are almost NEVER labeled as bromine or bromide.
3) You've got something causing heavy chlorine demand.
One way to check would be a pool use holiday -- 48 hours with no swimming. On the 2nd day, does in the late PM, test after 1 hour, and test again in the early AM. With 24 hours prior with NO swimming, the chlorine drop overnight should be very small. Then test again, at noon. If it's a sunny day, and you lose more than 20% of chlorine chlorine from sunrise to noon, EITHER your CYA test results are probably mistaken OR you have bromine or iodine in the pool.
If you do have significant chlorine drop from late PM the 2nd day to early AM the third day, I don't know what it could be.
If you have little drop overnight, and 10% or less loss from sunrise to noon . . . we'll need to look at what your swimmers are doing to create such a high chlorine demand.
Ben
Ben

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