You can probably improve your water more by adding borax, but that's pretty subjective and not everyone notices the difference.
Personally, I'd try to do what was needed with chlorine, and maybe borax, and leave the polyquat alone unless I really needed it. Borax is stable in pools; polyquat, for several reasons, is not.
Keep in mind that the general principle of BBB pool care is "Do what you need, and add what you need, and nothing else". Attempting to 'perfect' pool chemistry causes no end of pool problems. So, if you've got problem, fix it. But if not, leave it alone.
Ben
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