First of all, are you sure you have an algae problem? It is unlikely that at the high chlorine levels (relative to your 20 ppm CYA) you have algae. If your chlorine levels hold overnight, then you most likely do not have algae (so do they hold overnight?). If the water is cloudy, then this would be due to the very high pH over-saturating the water with calcium carbonate. This depends on the Calcium Hardness (CH) which you did not report, but even with a CH of 200 you might start to see some cloudiness and very likely at a CH of 300 -- again, due to the very high pH.
As for the cause of the pH rise, how rapidly did this occur (i.e. how often did you check the pH)? The pH will tend to rise in pools with high TA, but your TA isn't particularly high. If there was lots of aeration (including raindrops), it could have gone up, but usually not as high as 8.2. Were any chemicals besides chlorine added recently? Are you using only bleach or chlorinating liquid or are you also using Cal-Hypo for chlorine?
If the chlorine holds overnight, I would try lowering the pH first. Even if the pool had a green cast to it, that could be copper in the pool since the very high pH would force it to color the water green (from copper carbonate). Again, the overnight chlorine test is the easiest way to know if it's algae or something else.
Richard
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