A pH of 4 or above will very likely sting the eyes if you open them underwater. Other than that, you may not notice it unless you are sensitive. Skin is an amazingly tolerant "organ". If you look at the Wikipedia entry for pH, you will find a range of substances and their pH here. The pH of this pool was in between beer and orange juice. Skin seems to tolerate, in terms of "sensing", acidic conditions a little better than basic/alkaline conditions, though extremes of either are very harsh.
I think the bigger problem with the low pH would be dissolving of plaster. This pool measured 0 CH so is it a vinyl pool? Also, that's strange to measure no CH at all -- even the fill water should have some even if it's "soft".
Richard
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