In my honest opinion, go with synthetic wood decking too. I have come to the conclusion that wood is pure garbage, it warps, twists, curves, and does a million other things that I never want it to. I am seriously into not using wood for construction anymore. Of course the uprights and bracing I probably will, although if I find that there is an alternative to that then it is possible I would use synthetic there too.
But, screws for sure, nails outside are a temporary solution installed in a permenant manner. You cannot pull them easily, and they never really seem to stay put. Screws on the other hand, can be easily removed, and they tend to stay put.
Bookmarks