Well, I had a real "Aha!" moment when I put the Vit C against the stain. I came away clean as a whistle! That's why I love you all on this forum. I'd be totally lost about this pool without you guys.
An interesting thing also happened while I was in the pool trying out the vitamin C.
I have tried using a scrub sponge in the past with zero results. Today I accidentally brushed my foot along the coping edge and noticed that some of the stain came off so I tried the sponge on it.
I made my way all around the 16 X32 using my foot and the sponge (got lots of aquatic leg lifts in today!) and found that some of this stuff comes off down at the bottom of the pool. It didn't at all farther up the wall.
When I took the sponge out to look at it, there was rust colored stuff on it that rinsed out. Is this still metal too or do I have some algae?

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Sorry. Yes, you can wait till next year to clean up the stains - they will come off then, and maybe they will go away over the winter. You can get your water tested at some pool stores, or you can sometimes get it tested by your city. Where does your water come from? If it is from a well, then you will need to get it tested on your own, if it is city water they should be able to tell you what is in it. You won't need anymore cya regent until next spring. If your cya has been running around 30, then you are at the low end of cya and even if you are using trichlor pucks you probably didn't come up much. If I were you, I would close the pool this year, and before you open next year get some ascorbic acid, sequesterer, and new regents so you will be ready to go. You can do the stain treatment before you get your whole pool balanced, this way you will only have to do it once. As soon as it opens, take care of the algae (if the water is green) first. Then check to see if there is stains - I have opened to a stainfree pool every year, even if I had some at the end of the summer before. If you do have stains, do the stain treatment with sequesterer. Then balance the water, then have a wonderful summer
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