Please post your other numbers, especially pH, TA and CYA (temperature would also be nice) and if you are using Borates (Borax) in your pool at high levels (e.g. 50 ppm as opposed to just using Borax to occassionally raise pH).
I doubt that you are out of balance with water chemistry enough to cause corrosion, unless your pH and/or TA are quite low. I'll also need to know if the calcium you are buying is anhydrous calcium chloride or dihydrate calcium chloride (it should say on the container). You can usually just use the guidelines given on the container that will often say "add xx pounds per 10,000 gallons to raise calcium hardness by xx ppm" or something like that.
Richard
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