There is speculation that sunlight may help further the breakdown of combined chlorines, but we do not know for sure -- this is partly based on Ben's experience between outdoor and indoor pools where the latter usually have much harder problems getting rid of combined chlorine. The other difference between the indoor and outdoor pools is air circulation and this relates to your question about keeping the cover on during shocking. It is better to keep the cover off during shocking, not only to prevent damage from the higher chlorine levels, but to allow for good air exchange since the breakdown of chlorine from ammonia and nitrogenous organics will produce nitrogen gas. If you keep the cover on, then you will build up this gas under the cover and that will somewhat slow down the breakdown process (probably not a whole lot, however, since nitrogen is the main component in air already). There are also other volatile organics that would outgas from the pool more rapidly if a cover was not present.
Richard
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