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Thread: Calcium for metal

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  1. #1
    chem geek is offline PF Supporter Whibble Konker chem geek 4 stars chem geek 4 stars chem geek 4 stars chem geek 4 stars
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    Default Re: Calcium for metal

    Quote Originally Posted by RavenNS
    I heat my pool to 90F... would this indicate that i should have higher calcium levels to prevent corosion of the Heat Pump ( & filter pump)?
    ( I'm sure most people don"t regularly leave their pools that hot...lol)
    Actually, we run our pool, which is solar heated most of the time (for 5 months and gas heated about two months a year), at 88F since my wife uses the pool for swim therapy and I've always liked the warmer water temperature (I'm still pretty skinny).

    The best research on corrosion that I can find shows a rough doubling in corrosion rates for each 10C (18F) rise in temperature. The temperature inside a gas heater could be, near the metal surface, up to 30F higher so that is the most likely place for a problem (if any) but typically it isn't corrosion that people are worried about (since they keep their pH well above 7.0) but rather scaling since the higher temperature (ironically) makes it more likely to precipitate or scale calcium carbonate. So in plaster/grout pools, some people (Ben, for example) keep their pools on the slightly corrosive side so that the higher gas heater temperatures don't cause scaling. However, I've been educated on this forum by how extreme the water balance must get before either corrosion or scaling of plaster starts to occur (the LSI or equivalent index seems to tolerate even 1.0 without problems rather than the "official" 0.3 or 0.5 limit) so I really don't have a good answer except that we (including myself) probably worry about this too much.

    So if I were you, I wouldn't worry about corrosion or scaling and just keep you pH well into the normal range above 7.0. As far as temperature goes, spas are typically at 104F and I don't know if anyone adds calcium to spas nor have I heard of corrosion problems in spas that are not due to low pH. Of course, the relatively low volume of water in a spa compared to the relatively large number of people who can use a spa makes maintaining pH balance a real headache! Again, if anyone has any contradictory experience, I'd like to hear about it.

    Richard
    Last edited by chem geek; 08-10-2006 at 09:06 PM.

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    RavenNS is offline Established User Weir Watcher RavenNS Not to be trusted
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    Default Re: Calcium for metal

    ChemGeek, thanks for the leason... most facinating!
    ( how come i can totally get all this stuff that you post & I can't figure the darn test kits?...lol)

    As for Spa / Hot Tubs
    yes, you bet calcium is added... usually the companys bottle it up under a "different name" ( & charge at least 4 times as much for it )
    Beachcomber ( one of the tub brands that we have) have been selling us " Protect"... there is no content label on this stuff. I only found out that it was calcium this year, which means that I have been paying $13 a tiny bottle for quite some time for calcium

    The BBB method works just fine for hot tubs, just substitude bromine for Bleach...lol

    Oh & BTW, I find maintaining hot tubs is actually easier than pools... ( I dunno why)...lol
    Last edited by RavenNS; 08-10-2006 at 09:15 PM.

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    chem geek is offline PF Supporter Whibble Konker chem geek 4 stars chem geek 4 stars chem geek 4 stars chem geek 4 stars
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    Default Re: Calcium for metal

    Quote Originally Posted by RavenNS
    As for Spa / Hot Tubs
    yes, you bet calcium is added...

    The BBB method works just fine for hot tubs, just substitude bromine for Bleach...lol

    Oh & BTW, I find maintaining hot tubs is actually easier than pools... ( I dunno why)...lol
    Actually, I want to go off-topic here, so let me create a new thread for this. Please meet me at this linked thread.

    Richard
    Last edited by chem geek; 08-10-2006 at 10:21 PM.

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    chem geek is offline PF Supporter Whibble Konker chem geek 4 stars chem geek 4 stars chem geek 4 stars chem geek 4 stars
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    Default Re: Calcium for metal

    I just noticed in this post that Steve (medvampire) found that his pool with CH 350 and TA 200 gets cloudy when the pH gets above 7.8 so that means roughly a saturation index (LSI or CSI) of around 0.7 - 0.75 (depending on temperature which I don't know). So my statement about a 1.0 saturation index was true for one person, but not for another.

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