Assuming you are talking only about the frame and not about any part of the heater itself, it really wont make much difference, but you should make it white. The reason for this is that the lighter the color, the more heat is reflected back, and you want that heat reflected. However, now that I said that, it really is not going to make much difference. The solar tubes are black to absorb heat via radiation, which in turn is passed to the water through conduction and convection. Any additional heat reflected off the frame onto the black is minimal.
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