Re: How can TC be less that FC
Ok, I'll post it in this thread also
The DPD test uses 3 reagents. The first is a buffer solution, the second is DPD (N,N-diethyl-p-phenylendiamine) which turns pink in the presence of free chlorine. The color is compared on a comparator block to get the FC reading and then the third reagent, potassium iodide is added to get the TC reading once again using the comparator block. The FC reading is then subtracted from the TC reading to get the CC. The biggest drawback to the DPD test, besides the inaccuracy of the human eye and color comparator blocks, is that DPD will bleach out at chorine levels above about 10 ppm which could lead you to believe that there is NO chlorine when, in fact, the chlorine levels are very high. The sample can be diluted to overcome this but you will lose precision in the reading.
The FAS-DPD test (it stands for Ferrous Ammonium Sulfate- DPD) is performed by adding a buffered DPD powder to the water sample (10 ml). It will turn pink if chlorine is present. The sample is then titrated with the Ferrous Ammonium Sulfate solution until the pink color disappears and the sample turns colorless. The number of drops is counted and this is multiplied by 2 to get the FC readings (each drop= .5 ppm FC). Potassium iodide is then added and if any CC is present the solution will turn pink again. The sample is then titrated again and the drops counted...once again each drop= .5 ppm CC. If you want a TC reading you add together the FC and CC. This test will not beach out like the DPD test. If the sample bleaches out when the DPD powder is added you simply add more until the pink color stays. This way it is possible to test well over 20 ppm (possibly up to 50 ppm) FC. Also if the water sample size is increased to 25 ml the test becomes accurate to .2 ppm per drop instead of .5 ppm per drop.
Hope this explains it without confusing you too much.
Check out this page on the Taylor Technologies website for more info
http://www.taylortechnologies.com/Ch...P?ContentID=11
OTO (orthotolidine) is a test for TC only. It will turn yellow in the presence of chlorine. It is not the most accurate test in the world but it is 'bullet proof'. It won't bleach out and can give you a rough idea of high chlorine levels when you are familair with it. It's great for a quick daily test to make sure there is chlorine in your pool. The yellow colors of the OTO test are a bit easier to differentiate than the red colors of the DPD test but you cannot test FC with OTO (and it is not permitted for testing chlorine in commercial pools in most, if not all, states)
Retired pool store and commercial pool maintenance guy.
Bookmarks