Re: Does Ph naturally rise in the pool?
Pool water is intentionally over-carbonated to provide a pH buffer and to saturate the water with calcium carbonate to protect plaster pool surfaces. Such over-carbonation results in carbon dioxide outgassing and this causes the pH to rise over time. The rate of rise is related to the amount of over-carbonation which you can see from this chart that as the pH rises there is less over-carbonation so it slows down as the pH approaches around 8.4, depending on the TA level. You can see that a higher TA and lower pH is more over-carbonated so will outgas faster. The chart doesn't show the effect that the rate of outgassing varies as the square of the TA level, so a higher TA level can have the pH rise noticeably fast, especially if there is aeration of the water (waterfalls, spillovers, fountains, etc.).
15.5'x32' rectangle 16K gal IG concrete pool; 12.5% chlorinating liquid by hand; Jandy CL340 cartridge filter; Pentair Intelliflo VF pump; 8hrs; Taylor K-2006 and TFTestkits TF-100; utility water; summer: automatic; winter: automatic; ; PF:7.5
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