There is a sticky thread in the "Total Alkalinity" forum which explains how to reduce the TA number very effectively.
As far as the testing - I wouldn't do it right after you add chemicals - as they need time to distribute. CYA takes a few days to a week to dissolve.
My understanding is that the CYA in the tablets is minimal and that it is normally recommended to put CYA in at start-up to at least 30ppm. Then you can keep using the pucks until the CYA approaches 50ppm.
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