The only problem with storing Baking Soda and Borax is sometimes they get chunky--but are still effective. Bleach should be stored in a cool, dark place.
32k gallons is a pretty big pool--my A/G is a 40x16 foot rectangle, with 5' 6" deep zone, and it's still a bit less than 20k --about 19,200, or 19,300.
Generally, for estimating, once you are at that size, 1000 gallons higher or lower won't affect your calculations much. So if it's really only 31k or up to 33-34k it won't matter. Of course, if it's really 40k, and your estimating on the basis of 30k, that will matter.
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