Buy an 8' long piece of angle or channel iron, or all-thread rod. Have someone position and hold the end against the concrete, while a second person uses a small sledge hammer on the end that juts out above the water level to drive the iron rod into the concrete chunk.
Pre-arrange a method to signal the top-side person so you can control or stop the hammering in the event of a problem or the need to reposition the iron rod.
And keep your fingers clear.

You say you have air bubbles in the pump, is there a chance that the pipe itself was breached allowing the concrete in, in the first place? If so, have care removing the obstruction as you might cause a fatal leak in the pipe (using power equipment or excessive force is also not a good idea as the pvc pipe will probably give before the concrete). If the crete was just a glob that ended up in the pipe a good poke should have freed it, I fear the pipe was compromised before the crete was poured/ shot (pvc & crete don't bond very well).

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