No, there's nothing wrong with Soda Ash--just be careful, it's caustic.
Soda Ash DOES raise Total Alkalinity as well as raising pH--and if your pH was 6.8, it was probably lower--most kits measure down to 6.8, but no lower. If your pool is vinyl you want to get pH to 6.9, minimum QUICKLY!
Total Alk is fine up to 125ppm for concrete pools, up to 180 for vinyl. So you have to watch it when you use soda ash. If your Tot Alk is low, and so's your pH, Soda Ash is PERFECT. Otherwise, Borax is usually better for raising pH.
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