Just another reminder . . . the Langlier Index is popular among pool dealers because it sells chemicals, and not because it's especially applicable to pools!
It does matter *INSIDE* pool heater heat exchangers, but you MUST use the temperature INSIDE the tube (pool temp + 15 - 20 deg) and NOT the pool temperature.
It's also a rough guide to avoiding corrosion in plaster pools, and for allowing you to anticipate calcium carbonate precipitation in pools near theoretical saturation.
But, as Dr. Langlier himself noted, it doesn't really apply to bodies of water exposed to the air; only to closed systems like hot water heating systems.
What's more the whole issue of corrosion of plaster surfaces is far, far more complex than people realize. Sulfates, from things like sodium bisulfate or "dry acid", can be a big player. Aeration, from fountains or waterfalls, can have a huge impact. Plaster pools chlorinated with trichlor frequently show corrosion. There's even some preliminary evidence that high levels of CYA (> 150 ppm) can accelerate plaster corrosion.
What's reasonable is to keep a reasonable pH (7.2 - 7.8), a low to moderate alkalinity (80 - 140) and some calcium ( > 100 ppm on plaster pools ). There's very little evidence that pools maintained in such a way will experience plaster corrosion . . . ESPECIALLY if they are chlorinated with bleach or calcium hypochlorite.
Ben
"PoolDoc"
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