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Hi, Smokey,
Question 1 is an interesting thought. I wouldn't think so but that might be a possibility. If that is the case it will diminish quickly, I'm sure.
Question #2 is let your pool chemistry dictate. Once you get balanced out, you may not shock the rest of the Summer. Just test often enough to keep up with it.
If your water looks nice, I would keep doing what you're doing. If your water isn't where you want it to be, bring your Cl up to 25ppm and keep it there 'til it holds pretty close overnight. That would clear up any remaining issues you may have.....except for CYA and CH, of course. Just keep diluting when you can and let the rain help you.
You've done well in "getting it". Now, just keep applying what you know.
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