hello Kevin, and welcome to the forum.
First off, "chlorine block" doesn't exist. It's often a way for pool stores to try to give answers about pool problems when they're not sure of the problem. When you have an algae bloom, you need to take the chlorine up to "shock" level, which in your case is 25 ppm, and hold it there until the pool clears by testing and adding more chlorine as many times a day as possible. In your case, if the pool has turned blue, you may be through shocking and may not--you can tell by testing at night after the sun is off the water and then testing again in the morning before the sun hits the pool--if you've lost more than 1 ppm chlorine, then you're not finished yet, and you need to get the chlorine back up to 25 ppm and hold it there until you don't lose chlorine overnight. Since your pH is so low and your CYa is so high, I'm guessing that you're using trichlor tabs to chlorinate and maybe dichlor powder to shock with? You need to stop using any stabilized form of chlorine at this point, because your CYA is so high that you're going to have to run a higher baseline chlorine level to compensate in order to keep algae away. You can check out the "best guess chart" in my sig, but with a CYA of 100, this means that after the shocking process is finished and the pool is cleared up, you must keep your chlorine in the 8-15 ppm range at all times to keep from getting another algae bloom. The higher the CYA, the higher the chlorine levels you must keep.
You also need to get that pH up above 7.0 as soon as you can--anything below 7.0 is acidic and can damage your pool liner. We suggest Borax for this--added through the skimmer very slowly, breaking up clumps, allow a couple of hours to circulate and then test again, adding more if necessary. You want to target 7.2-7.6. I would start with 1/2 box in your case, and go from there. Do this before taking your chlorine back up, though, because chlorine above 10 ppm can cause falsly high pH readings.
In a 20K gallon pool, each 1.5 quarts of 6% bleach will raise your FC by 1 ppm, and each 1.5 gallons will raise your FC by 4.5 ppm, so you can use that as a guide when figuring your bleach.
We don't really recommend the Nature II units--I know they advertise that you can run lower levels of chlorine with them, but that is very difficult to do without an algae bloom, and they do add copper to the pool, which results in staining the pool, blonde hair, fingernails, etc green. You can use the google link my my sig to look around the forum for other posts on the Nature II.
Janet
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