Thanks all for your input. Those stains could indeed have been caused by leaves as the pool basically sat during the winter months. It was covered, but there was still some debris in the water when we uncovered. Also, I was just seeing the beginnings of mustard algae, so I used some Yellow Treat, brushed, shocked, and ran filter appropriately.
My pool's PH generally stays around 7.4 - 7.6. However, I read in a couple of places that the PH should be lowered and chlorine discharged (used up) before using ascorbic acid. At the time of my post, I really thought this was some kind of stain caused by metal, but trying the ascorbic acid didn't help. That's when I figured it was a non-metal stain. However, I am pretty certain it's not black algae, as I had dealt with a few spots of that in my spa a few years ago.
To make a long story longer, I shocked last night and the stains seemed much, much lighter this a.m. I'll continue that route, I guess.
I will post my numbers when I get home and test the water. I'm still puzzled as to what caused such bad staining. I guess it could have been leaves...
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