It is okay to add the dichlor through the skimmer as long as you don't have trichlor in a feeder--you never want to mix forms of chlorine outside of the pool water itself. Just either sprinkle it in slowly so that your pipes don't choke, or you could pre-dissolve it in a bucket of water and pour it in that way. I don't think you're going to see a noticeable rise in CYA until after several pounds, so I wouldn't waste the reagent just yet.
Polyquat is much more efficient at preventing an algae bloom than it is in clearing one up--so if you're fighting an algae outbreak, I'd hold off on the polyquat. Many people on this forum just use it for closing up for the winter, and some of us don't use it at all. The polyquat will quickly consume the chlorine you're putting in, so I would just leave it aside for now and concentrate on chlorinating the heck out of your algae.
Janet

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