A CYA of 100 is WAY too high. And, in actuality, it may be much higher than 100 as that is as high as most test kits can register. Please do NOT add more CYA. I bet the previous owner used trichlor pucks for the source of chlorine for this pool. Trichlor is stabilized and adds CYA with each puck added to the pool. The only way to lower the CYA is to drain and refill. Having said that, you don't ever want to totally drain a pool, especially in a swampy place like Louisiana. Doing so can cause the pool to pop up out of the ground.
You have a couple of options. Option 1 You can either slam it with bleach and eradicate the pool of algae now and then once the pool is clear, you can do several partial drains and refills until you get the CYA to a more manageable level. (Unfortunately, it will take a lot of water replaced probably a couple of times. In a big pool like yours, that may be a substantial amount of water.) if you decide to do this, it will take shocking it way higher than 15 as I originally suggested. With a CYA that high, you'll need to keep the chlorine level at 25-30 to kill the algae. (Required chlorine levels depend on the CYA level in a pool.)
Option 2 is to go ahead and do the partial drains and refills now before adding the bleach. Then, you can attack the algae later. (That will save you some money in bleach.)
Option 3, and the least desirable one in my opinion, is to live with a high CYA level. But, you will have to run higher than normal chlorine levels as a result meanng that you will always have to keep your chlorine between 8-15 all the time or you risk another algae bloom.
Let us know what you think and we'll wallk you through any of these options.
The good news is that once you get the CYA level down to a more manageable level, we can teach you how to keep this from happening again.

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