Re: using citric acid to remove metal stains...
Pool size is in my signature - 27,000 gallons. 
I only put in a one pound box of baking soda so far. (The pool calculator site says I'll need five.) I had to add water last night and didn't want to bring up the pH too quickly, just like you wrote. I will hold off until I can get in there with the Vitamin C tablets to finish off my stubborn stains. (And get the chlorine stable.)
I'll look for calcium hypochlorite at the pool store (my once-annual trip, I suppose) to try to hit two birds with one stone. I realize that more calcium will be needed than just what is in chlorine though.
about 27,000 gal IG w/spa
Polaris cleaner
Autopilot SWCG
Pentair cartridge filter
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