How soon you can check the chems after an addition depends on how well your pump circulates the water. I usually wait a couple of hours before testing again.
As to how often to test, I check pH and FC/CC every day, TA once a week, CYA once a month after I have it where I want it to be. Because our pool has a lot of splashout from the dogs we refill almost daily and have considerable dilution of CYA and have to adjust it more frequently.

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He specializes in doing things the hard way. LOL! He's very scientific about everything! To be fair, he says the bottle is an odd size, so it makes it hard to measure it. I think we'll find an old pitcher or something and make quart and/or pint markings on it and use it for adding bleach, so we can do it the easy way, but for now, he's still doing it the technical way.

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