Re: any way to control pH better?

Originally Posted by
PoolDoc
I can observe that, in my experience with multiple large commercial pools managed with sodium hypochlorite (bleach) feed systems, I universally found that bleach fed pools 'wanted' to be at a pH of 7.6 or higher. I have no analytical explanation for this. But I can tell you that I discovered that if I let the pH float upwards, it usually -- but not always -- stopped before 8.0. I also found that if I operated the pools between 7.6 and 8.0 it took FAR less acid, than if I tried to operate the same pool between 7. 2 and 7.6. (Note to Chem Geek: yes, I tried it both ways on the SAME pools

)
I have seen the same effect on customer's pools with SWGs and on the commercial pools with bleach feed systems also, and have discussed this before on different forums.
Most buffers have ranges over which they are effective, and other ranges over which they are not so effective. Cyanuric acid is an effective buffer at LOW pool pH levels, below 7.4 as I recall. Borax is an effective buffer at HIGH pH levels, above 8.0, I think.
At normal pool pH range most of the borate/boric acid buffer is in the form of boric acid and has a downward effect on pH when it starts to climb as opposed to the bicarbonate/carbonic acid buffer which causes ph to move toward 8.2
Just my 2 cents.
Retired pool store and commercial pool maintenance guy.
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