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Madty
04-17-2006, 11:42 PM
Will stabilizer lower PH? The reason I ask is that I put in 3 lbs of stabilizer to raise my level 10 ppm. I also put in 1/2 gallon acid. Later on I read the test and the PH was around 6.8- light peach color. Previously it was 8.2. I didn't think 1/2 gallon acid would do that much to ph- btw 26,000 IG vinyl

waterbear
04-18-2006, 12:15 AM
stabilizer will cause a lowering of the pH. It is cyanuric acid with the operative word being acid. Just make adjustments slowly with borax to bring it up. As the CYA dissolves and combines with the chlorine in the pool the pH will come up a bit on it's own so don't overcompensate!

aylad
04-18-2006, 08:17 AM
Will stabilizer lower PH? The reason I ask is that I put in 3 lbs of stabilizer to raise my level 10 ppm. I also put in 1/2 gallon acid. Later on I read the test and the PH was around 6.8- light peach color. Previously it was 8.2. I didn't think 1/2 gallon acid would do that much to ph- btw 26,000 IG vinyl
Yes, 1/2 gallon of acid WILL do that much to a 26K gallon pool. Take your time when adding chemicals--it's much better to "sneak up" on your target number than it is to overshoot it and have to correct the new problem!

Janet

Madty
04-18-2006, 09:02 AM
Yes, 1/2 gallon of acid WILL do that much to a 26K gallon pool. Take your time when adding chemicals--it's much better to "sneak up" on your target number than it is to overshoot it and have to correct the new problem!

Janet

Thanks Janet- For some reason, I thought a gallon would move it a little. What's a good rule of thumb for lowering PH by x amount? Or is it simply do a little then wait and retest.

Also what should I do now to bring it back up. Wait a couple of days since I added stabilizer, salt, acid etc... My pool is actually getting very clear.

Madty
04-18-2006, 09:03 AM
stabilizer will cause a lowering of the pH. It is cyanuric acid with the operative word being acid. Just make adjustments slowly with borax to bring it up. As the CYA dissolves and combines with the chlorine in the pool the pH will come up a bit on it's own so don't overcompensate!

Yeah, I guess I added acid twice- I will add a little borax and see what happens!

duraleigh
04-18-2006, 10:42 AM
Folks,

We've gotten off track. His original question asked if 3lbs of stabilizer would have a dramatic affect on his pH (8.2 down to 6.8).


stabilizer will cause a lowering of the pH. It is cyanuric acid with the operative word being acid. Just make adjustments slowly with borax to bring it up.

The above statement is simply incorrect....given the intent that the questioner asks, 'could his CYA and the 64 oz of muriatic he added have affected his pH that much?' There is no chance That adding 3 lbs of CYA to a pool will DRAMATICALLY decrease the pH. If that were true, imagine what the pH would've done if he had tried to raise it by 40ppm!!

using Michaels calculator, it looks like a 26k pool needs 1.15 gallons of muriatic to lower the pH by 1.4.

How was the testing conducted? Have you tried the same test again? I think the accuracy of one or both of the tests might be an issue.

Mad, run your tests again and be really sure your pH is where you think it is. Raise and or lower it with Borax and Muriatic Acid. Use Michaels calculator to figure your quantities. The affect CYA will have on your pH will be FAR less dramatic than implied above.:) :)

Dave S.

kaybinster
04-18-2006, 05:11 PM
It is not possible to tell how much the pH would drop by adding the acid unless you know the alkalinity of the pool. If you recall high school chemistry you may remember something about buffers - they tend to hold pH at their current level and its only when you exceed that level does the pH change. Thus, the higher the alkalinity the lesser impact you will have on the pH.

PoolDoc
04-19-2006, 11:40 AM
It is not possible to tell how much the pH would drop by adding the acid unless you know the alkalinity of the pool. If you recall high school chemistry you may remember something about buffers - they tend to hold pH at their current level and its only when you exceed that level does the pH change. Thus, the higher the alkalinity the lesser impact you will have on the pH.
Kay, you're right, but most people never had high school chemistry, and most of those no longer remember what a buffer is. So, you need to include more info, with an answer like that.

Everybody else . . . Kay's answer is both correct, and relevant. Mike's Calculator has a embedded caution that acid doses are very approximate. But, I've learned -- repeatedly -- that what seems like a large warning to me, is still overlooked by about a zillion of the folks who see it.

The bottom line is that it's not possible to know, from pH alone, how much a given dose of a particular acid or base will change the pH in your pool. More than that, you can't even predict the change accurately if you have BOTH the pH level and the alkalinity level. After all, the pool alkalinity test is ACTUALLY nothing more than a measurement of how much acid it takes to move your pool's water from it's current pH, to a pH of 4.6!

Taylor's K2005/6 testkits included vials of acid and base, so you could perform "Acid Demand" and "Base Demand" tests which -- in theory -- allowed users to accurately determine exactly how much acid or base to add. In theory . . .

But, in practice, those tests caused no end of problems. The problems began with a systematic error in one of the Taylor charts (now corrected -- I forget which one it was). But, there were all sorts of other problems as well. Just to mention one: few people have the capability to accurately measure doses of acid or base BY WEIGHT. But, if you are going to use the AB demand test, that's just what you have to do.

These problems, and others, meant that users who tried to use the AB rarely got it right, and often overshot their target, creating a new problem that had to be corrected!

As a result, the very first change I made in the K2006, when I began modifying it, was to dump the AB tests, and add an extra vial of R-13 reagent.

Folks, I've said it before: if you are selling chemicals to pool owners, you need to be able to calculate one shot treatment doses. Your customer won't want to return for three more tests, and small purchases of, say, acid. But, if you are a pool owner, there is NO benefit to trying to adjust the pH all at once. You should be testing your pool frequently, anyhow -- use small repeated doses, and you'll get there without causing more problems.

Good luck!

Ben

To return to the original poster's ? -- CYA does lower pH, but the effect is usually not noticeable, among results of all the other things that affect pH. The change noted came from the added acid, not the CYA